State estimation for gas purity monitoring and control in water electrolysis systems

원문 초록

Green hydrogen, produced via water electrolysis using renewable energy, is seen as a cornerstone of the energy transition. Coupling of renewable power supplies to water electrolysis processes is, however, challenging, as explosive gas mixtures (hydrogen in oxygen) might form at low loads. This has prompted research into gas purity control of such systems. While these attempts have shown to be successful in theoretical and practical studies, they are currently limited in that they only consider the gas purity at locations where composition measurements are available. As these locations are generally positioned downstream of the disturbance origin, this incurs considerable delays and can lead to undetected critical conditions. In this work, we propose the use of an Extended Kalman Filter (EKF) in combination with a simple process model to estimate and control the gas composition at locations where measurements are not available. The model uses noise-driven states for the gas impurity and is hence agnostic towards any mechanistic disturbance model. We show in simulations that this simple approach performs well under various disturbance types and can reduce the time spent in potentially hazardous conditions by up to one order of magnitude.