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arXiv:2611.11074v1cs.LG

System Prompts Affect Response Bias More Than Discriminability in LLM Safety

Large language model safety evaluations often focus on a compliance-refusal tradeoff: models should refuse unsafe requests without refusing safe ones. We argue that this misses a broader form of prompt-conditioned task selection, where the same request can elicit different behaviors depending on the system prompt. We investigate this using a controlled evaluation crossing eight safety-task prompt families with three clarity levels across HarmBench, XSTest, and IHEval. Holding benchmark items fixed, we evaluate 13 models and use signal detection theory to distinguish two possibilities: whether models become better at telling safe from unsafe requests (discriminability), or simply more willing to refuse (response criterion). We find substantial differences in discriminability across models, but system prompts primarily shift the willingness to refuse, with smaller and less consistent effects on discriminability. Increasing prompt clarity makes models more willing to refuse without reliably improving their ability to distinguish safe from unsafe requests. Beyond refusal, prompt families also shift responses among six distinct behavioral policies, including clarification and safe help. Together, these findings show that system prompts primarily change how models respond to safety-relevant requests rather than consistently improving their ability to distinguish safe from unsafe ones.

arXiv:2611.11071v1cs.CV

NanoNet: Ultra-Lightweight Network for MRI Brain Tumor Classification toward Edge AI

Automated brain tumor classification from magnetic resonance imaging (MRI) can support accessible medical image analysis, but conventional deep learning models often exceed the resource budgets of highly constrained edge-AI platforms. We present NanoNet, an ultra-lightweight convolutional neural network designed for resourceconstrained MRI classification and motivated by future edge-AI applications. Inspired by MobileNetV2, NanoNet substantially reduces network depth, channel capacity, expansion ratios, and final feature dimensionality, resulting in only five inverted residual blocks and 8,132 parameters. We further investigate dependency-aware structured pruning, knowledge distillation, and INT8 quantization-aware training for additional compression. Experiments on the BRISC 2025 benchmark show that NanoNet achieves 92.80% accuracy and 92.97% macro F1 with 8,132 parameters and 10.498 MFLOPs. Across three compression seeds, it exceeds the mean accuracy of 70%-pruned MobileNetV2 by 5.20 percentage points while using 60.2% fewer parameters and 9.8% less computation. Converted INT8 NanoNet achieves 89.70% accuracy and 90.22% macro F1 across three QAT seeds. Earlier TensorFlow Lite measurements indicate 27.7 KB of baseline model storage, motivating future edge-AI deployment.

arXiv:2611.11068v1cs.LG

Discrete Diffusion Playground: A 2D Benchmark for Discrete Generative Models

Discrete diffusion is a promising framework for categorical generative modeling, but current evaluation protocols often fail to reveal whether models have actually learned the target distribution. We introduce the Discrete Diffusion Playground, a diagnostic benchmark that converts known 2D continuous distributions into binary token sequences through an exact discretized bijection. This creates a rare setting in which models are trained on discrete sequences, but generated samples can be decoded back into 2D and compared directly against a known ground-truth distribution. The benchmark spans smooth Gaussian mixtures and tilted checkerboards with sharp boundaries, disconnected support, and coordinate-dependent structure, allowing it to expose failures that are invisible in standard proxy metrics. It supports exact grid divergences, Wasserstein distances, density visualizations, and nonparametric two-sample tests, providing both quantitative evaluation and interpretable failure diagnosis. Using this testbed, we show that masked diffusion models can learn meaningful adaptive reveal orders but remain less stable than autoregressive baselines on smooth targets and largely fail on tilted checkerboards, where autoregressive models preserve the target geometry. Control experiments with reversed and interleaved token orderings show that autoregressive performance is not explained by favorable bit order alone. The Playground provides a simple but stringent benchmark for stress-testing discrete generative models and for developing evaluation metrics that detect real distributional mismatch rather than proxy performance. Our code is available at https://github.com/shaojus/DiscreteDiffusionPlayground .

arXiv:2611.11067v1cs.CR

Beyond AUROC: Deployment-Aware Evaluation of Model-Internal Jailbreak Detectors

Large language models (LLMs) are increasingly deployed in user-facing systems, where jailbreak attacks can bypass safety controls and induce harmful and policy-violating outputs. Recent model-internal detectors use hidden representations, gradients, or internal signals to identify such prompts, but their practical security value depends critically on behavior at low false-positive operating points rather than on area under the receiver operating characteristic curve (AUROC) alone. We study two data dependencies that shape this behavior: calibration data, which determine the detection threshold, and reference data, which can influence detector scores. Across four model-internal detectors, four LLMs, and twelve jailbreak families, thresholds calibrated on curated benign prompts frequently fail to preserve their false-positive rate (FPR) budgets on real-user traffic. Recalibration improves false-positive control but reveals substantial family-level coverage gaps, including cases with high AUROC but low true-positive rate (TPR). Causal reference-set interventions show that changing reference composition can substantially alter family-level detection and that improving coverage of one attack family can reduce coverage of others. These findings show that calibration and reference data are part of a detector's security behavior. We therefore recommend evaluating model-internal jailbreak defenses using realized FPR on deployment-like traffic and per-family TPR at explicit low-FPR operating points, with AUROC used as a complementary ranking metric rather than the primary security measure.

arXiv:2611.11066v1physics.ao-ph

Rescene-ESM: an Earth system model built around a frozen AI weather model

Earth system models underpin climate projections, but their cost limits how many scenarios, ensemble members and impact pathways can be explored. Machine-learning weather models forecast as skillfully as physics-based models at a fraction of the cost, yet coupled to an ocean they have produced weak El Nino variability or have learned it from climate-model output, and none carries the climate through rivers to the people exposed to it. Here we present Rescene-ESM, an Earth system model whose coupler, YAHO, yokes a frozen 20.8-million-parameter AI weather model to physically formulated ocean, sea-ice, land, river, carbon and energy components constrained by observations. Adding the couplings one at a time shows what each contributes: over a climatological ocean the AI atmosphere varies from year to year by a third of the observed amount over the oceans, and an interactive mixed layer, an equatorial wave ocean, the residual of the observed sea surface temperature (SST) equation as stochastic forcing and the land's moisture flux raise this step by step and bring El Nino and its teleconnections, leaving the mean climate almost unchanged. The full model simulates about 1,000 years per day on one graphics processing unit, holds the observed climate for a thousand years without drift, reproduces the observed 1979-2022 global warming, carries forced change with a physically based structure around the frozen network (transient climate response 1.60 K), routes runoff to 212 river gauges with a median seasonal-cycle correlation of 0.79 and, driven by emissions, separates the heatwave exposure of an SSP1 and an SSP3 world by a factor of 4.7 in 2081-2100, three-quarters of it through the warmer climate.

arXiv:2611.11064v1cs.AI

GARP: Real-Time Generative Agents on Local Hardware in a Game Engine

Generative agents are game characters whose plans, conversations, and memories are written on the fly by a large language model (LLM). The original Generative Agents demonstration used cloud inference in a custom simulation. We present GARP, a platform for real-time generative agents inside Godot, and describe the Character Behavior System used in GARP 2. The complete loop runs on local hardware using a 3B-parameter open-weight model and no cloud service. Alongside the original planning, memory, and reflection, GARP gives each agent an emotion system driven by LLM appraisal, four graded personality axes drawn from the Big Five that set simulation parameters as well as prompt text, six needs whose urgency grows over time, and pairwise relationships updated after every conversation. The system narrows 50+ candidate actions to typically 3-8, constrains model responses with JSON schemas, and surfaces important memories in decision prompts. A layered optimization strategy (an adjustable game clock, decisions taken ahead of need, multi-tier caching, prompt compression, and fully asynchronous execution) keeps the game responsive while the model thinks. In a nine-scenario evaluation, 25 of 27 runs passed log-based checks. Both failures occurred in the birthday party scenario, where one guest omitted the event from their daily plan.

arXiv:2611.11063v1cs.LG

Target Recoverability under Selective Labels: A Failure Mode in ECG-Based Acute Coronary Syndrome Prediction

Medical machine learning models often learn from diagnoses observed only in patients clinicians chose to test. The biases of such selective labels are well known, but less understood is what happens when a diagnosis includes cases the model's inputs cannot detect. Because testing decisions draw on information the model does not see, these cases can appear predictable among tested patients, producing relationships that fail, and can even reverse, among the untested. We formalize this mechanism and show in simulations that it worsens as testing becomes more selective or undetectable cases more common, while models trained only on detectable cases remain informative. We empirically study electrocardiogram (ECG)-based prediction of acute coronary syndrome (ACS), which is confirmed only by invasive testing and whose subtypes differ in how clearly they appear on the ECG. Three ECG foundation models fine-tuned on revascularization, our ACS proxy, performed well among catheterized patients (AUROC 0.740-0.770) but worse than chance for 30-day major adverse cardiovascular events among untested patients (AUROC 0.381-0.478). Models trained on ECG-visible subtypes retained discrimination (AUROC 0.680-0.709), whereas a model trained on unstable angina, which can occur without ECG changes, was inversely related to risk (AUROC 0.310). Under selective labels, effective learning therefore requires prediction targets that can be inferred from the model's inputs and evaluation in the intended deployment population, which often extends beyond the patients who were tested.

arXiv:2611.11062v1cs.CV

What Does Multiple Choice Actually Measure? Disentangling Video Understanding from Option Exploitation

Video understanding evaluations are intended to measure a model's proficiency in video perception and task solving. However, current VideoQA benchmarks struggle to isolate these capabilities due to their reliance on multiple-choice (MC) answer guidance, language priors, and fragile scoring pipelines. Disentangling these confounding factors reveals how much of a model's score is supplied by the evaluation context rather than earned through faithful perception. Across six VideoQA benchmarks of varying length, we find that accuracy is significantly above chance without any visual input. This is caused by shortcutting and option-prior reliance. We express these effects in the language of faithfulness: option-exploitation and answer-conditioned reasoning traces are unfaithful even when they are correct. Together, our results show that a VideoQA score is jointly determined by language priors, option timing, and how outputs and labels are converted into correctness. We produce a novel Option-Delayed Replay (ODR) mechanism that discloses options at controlled stages of an open-ended (OE) trajectory, to obtain objective MC scores from faithful option-free inference. Our work demonstrates that agentic methods with ODR and faithful inference can match option-exploiting performance. Finally, we formalize our diagnostic collection and ODR as a reproducible evaluation protocol, and we release a human-relabelled edition of LVBench (correcting $20.5\%$ of keys) to remove annotation noise as a confounding variable.

arXiv:2611.11061v1physics.acc-ph

Symplectic Normal Coordinates Flow for Generative Modeling of Hamiltonian Systems

In conditioned generative models of physical systems, the densities at different values of the conditioning parameters are often related through symplectic transformations. For stable linear Hamiltonian systems, there exists a symplectic transformation to "normal coordinates" such that the dynamics is reduced to rotations in each phase-space plane. This picture extends to the nonlinear case where, away from resonances, the Birkhoff normal form again consists of rotations in phase space, now with amplitude dependence. In this work, we introduce an invertible symplectic flow layer consisting of amplitude-dependent rotations in learned normal coordinates. We derive the condition under which the nonlinear rotation layer is symplectic and detail an architecture that guarantees it. Experiments are carried out on three conditional generative modeling problems: a synthetic chain of coupled nonlinear oscillators and two problems from accelerator physics. We show empirically that normalizing flows with the new layers achieve competitive or superior negative log-likelihoods compared to baseline flows, with gains that grow with the strength of the nonlinearity on the synthetic system.

arXiv:2611.11058v1cs.CV

Differentiable Virtual-Slot Partitioning for Adaptive Tokenization in Vision Transformers

Adaptive tokenization aims to reduce the compute spent on uninformative image regions while preserving accuracy. Existing work relies on (i) fixed or frozen scoring rules, which cannot be trained toward the task loss, or (ii) discrete masks trained with straight-through estimators, which yield noisy gradients, while fully differentiable alternatives instead leave the pre-trained regular grid. We revisit adaptive tokenization from a regular-grid perspective and ask: can a two-scale quadtree be learned end-to-end without deleting a single token during training? We show that one coarse token and its four fine children can be made the two endpoints of a single continuous interpolation. We introduce Differentiable Virtual-Slot Partitioning (\dvsp{}), which keeps four \emph{virtual slots} per $2{\times}2$ region and blends their token features and attention mass with a single weight $\alpha$, exactly reproducing the discrete grid at $\alpha \in \{0,1\}$. On COCO detection with EVA-02-B, \dvsp{} retains $97.9\%$ of dense Box AP while removing $64.2\%$ of visual tokens, giving a $1.61\times$ end-to-end speedup, and it outperforms entropy-based APT, DART, and uniform lower-resolution dense adaptation at matched budgets; these gains depend on the conserved attention mass, whose removal costs $1.59$ Box AP. On a frozen Segmenter it also improves Cityscapes mIoU, and on frozen DeiT backbones it exceeds entropy selection at identical per-image token counts.

arXiv:2611.11055v1cs.AI

But It Was True When I Checked: Compiling SHOP-Style Method Preconditions into Partially-Ordered HTN Planning

Method preconditions specify when a method may be applied in hierarchical task network (HTN) planning, but their meaning differs under two established semantics. The SHOP planners, like the classical HTN formalism of Erol, Hendler and Nau, require the precondition to hold immediately before the method's first action. HDDL, the input language of the International Planning Competition's HTN track, instead introduces an auxiliary action to check it; under partial order, unrelated actions may invalidate the precondition before the method starts. HDDL's designers adopted this weaker semantics because the first-action reading could not easily be compiled. Subsequent work has repeatedly identified its compilation under partial order as an open question, with existing transformations limited to total order. We give a compilation of the first-action semantics into standard partially ordered HTN planning without method preconditions using only two additional facts, thereby resolving a longstanding question in the HTN planning community.

arXiv:2611.11053v1cs.NE

Neural Activity Synchronization-Based Fast Local Learnable Spiking Neural Network Architecture

Implementing intelligent learning systems on low- power edge devices is challenging due to the high compu- tational complexity, training latency, and energy demands of traditional Artificial Neural Networks (ANNs). Spiking Neural Networks (SNNs), biologically plausible and spike-driven, come as an alternative. However, SNN training commonly relies on backpropagation through time (BPTT), which is computationally expensive, inherently global, and unsuitable for battery-driven devices. This work proposes a novel local learning framework for multi-layered SNNs inspired by Neural Activity Synchronization (NAS). Each layer updates its own weights using locally com- puted gradients. No gradient backpropagation is needed. This significantly reduces computational complexity, training latency, and energy consumption. The proposed SNN model is trained and evaluated on the MNIST dataset, achieving a classification accuracy of 97.78%. The model is also analyzed with Gaussian and salt-and-pepper noise, demonstrating robust performance across different noise levels.

arXiv:2611.11045v1cs.DB

Agents Propose, Code Verifies, Humans Decide: Verified Agentic Ingestion of Heterogeneous Scientific Tables into Relational Databases

Public scientific datasets rarely arrive analysis-ready. They arrive as messy folders of wide matrices, long tables, spreadsheets, and per-cohort files whose keys and encodings differ, and every reanalysis must reconnect them first. A coding agent can automate this, but its mistakes can look plausible, and without an audit trail, a mistake that corrupts data can go uncaught. We present an AI-assisted ingestion pipeline built on one rule: LLM agents propose, deterministic code verifies, and humans decide. Narrow agents see compact, citable evidence about the files, never the data, and return typed proposals. A verifier with 39 check types tests each proposal against that evidence in two loops, one for the schema's structure and one for its meaning, and a human reviewer approves the schema and the load. Code compiles PostgreSQL DDL, reshapes the data, quarantines rows it cannot place, records provenance, and reconciles every staged row against the database. On four public biomedical datasets, one held out from development, 9 of 20 first proposals failed a check and every failure was caught: the loops repaired eight, and a one-line reviewer edit fixed the ninth. All 45.1 million values loaded with zero reconciliation gap. Discovering a dataset's structure took 4-7 LLM calls and preparing its data at most one more, costing under $0.50 per dataset. In a separate test, each of nine planted data errors was quarantined with a reason or recorded in an audit log.

arXiv:2611.11041v1cs.CV

Virtual Task Prompting for Multi-Task Scene Understanding

Multi-task scene understanding models typically rely on modified vision encoders or complex decoders for cross-task interaction, which limits their flexibility and compatibility with off-the-shelf vision foundation models (VFMs). We introduce Virtual Task Prompting (VTP), which frames multi-task prompting as retrieving task-adaptive compositions from a shared virtual state, where both the state and routing process are optimized in an end-to-end manner. Concretely, VTP maintains an expanded set of virtual tasks alongside the backbone. At each layer, learnable routing matrices read task-specific compositions as input to interact with image tokens and write the processed results back, forming explicit pathways that capture the intricacies among tasks outside the encoder. Since VTP keeps the backbone clean, it integrates seamlessly with pretrained VFMs, advancing the state of the art on Pascal-Context and NYUD-v2. Stress test on Taskonomy with 13 heterogeneous tasks further shows VTP's robustness in extreme settings. Ablations and analysis indicate that VTP's gains stem from adaptive routing rather than increased capacity. The project page is available at https://jacky1128.github.io/VTP/.

arXiv:2611.11040v1cs.SE

Advancements in Cloud-Native Systems: A Systematic Mapping Study of Reliability and Scalability across Cloud-Native, Edge-Native and AI-Enabled Systems

Cloud-native systems now extend to the network edge and host artificial-intelligence (AI) workloads, including AI agents, but evidence on their reliability and scalability is scattered and uneven. We report a PRISMA 2020 systematic mapping study with an evidence-graded synthesis. Five logged OpenAlex searches on 11 October 2026 covered cloud-native systems, edge AI, agentic AI for operations, reliability of agentic applications and physical AI; 189 records from an earlier exploratory search were added separately. After 301 duplicate removals and an automated peer-review venue rule, 4,611 records were screened against written criteria and a five-level relevance scale. The review includes 1,794 primary studies from 2017-2026 and 95 secondary studies, with every decision released in Dataset S1. Each primary study was assigned to a 13-category taxonomy and graded as simulation, prototype or testbed, production data, production deployment, or not determinable from the abstract. Of 1,003 studies with a determinable level, 66.2% used prototypes or testbeds, 18.0% simulations and 15.8% production data or deployments. A 93-study synthesis core, appraised from indexed abstracts, shows production deployments of cascading-failure prevention, trace- and graph-based root-cause analysis and predictive autoscaling, and production-trace evaluations of cold-start mitigation. Edge reliability and physical AI rely mainly on simulations and testbeds. AI-agent reliability uses tool-grounded diagnosis, explicit safety properties, trace-driven repair and workload-aware scheduling, while empirical studies show that agent frameworks remain fragile. Conclusions are limited to the documented corpus. The principal gaps are production evidence for edge-native systems, shared resilience benchmarks and dependable agentic operations.

arXiv:2611.11035v1cs.CL

Room to Reconsider: Reply Length Decides Whether Pushback Makes Language Models Sycophantic or Self-Correcting

Language models often abandon a correct answer when a user pushes back without giving a reason, and this behavior is usually studied as sycophancy to be suppressed. The same pushback, however, also leads models to revisit and sometimes repair a wrong answer. We measure both effects on multiple-choice questions from MMLU and ARC-Challenge with four open models from two families (Qwen3 1.7B, 4B and 8B, and OLMo-2 7B), reading the final answer exactly from option logits after a free-form reply. The reply budget changes the verdict. When Qwen3-4B may answer the challenge in at most 96 tokens, pushback leaves accuracy unchanged or slightly lower; with 1,024 tokens, it corrects 43% of its wrong answers and pushback raises accuracy by 5.7 points. Whether pushback helps overall follows a simple break-even rule in the cave and correction rates. Inside the model, caving can be partly predicted before the challenge: hidden states add about 0.04-0.06 AUROC over turn-1 confidence in three of our four probing runs. A probe trained only on self-correction cases predicts caving beyond confidence when replies are truncated, but not when the model can finish its reasoning. Activation steering never reduced caving selectively: where it worked, it suppressed self-correction as well. We conclude that sycophancy evaluations should allow full replies and report self-correction alongside caving.

arXiv:2611.11034v1cs.LG

Prune to Probe: Causal Decision-Stability Probes for Efficient Reasoning

Reasoning models often continue generating after producing an answer, yet stopping prematurely may interrupt useful verification or revision. In this work, we investigate whether targeted interventions in a model's internal computation can provide a reliable signal for when to stop reasoning. We introduce Prune-to-Probe, an inference-time controller that uses causal activation interventions to probe the stability of a model's current answer. Specifically, we identify late-MLP coordinates that contribute to post-answer continuation while excluding those important for answer completion. Once an answer is stated, Prune-to-Probe temporarily suppresses the selected coordinates and measures the resulting stopping response relative to matched random interventions. Crucially, these interventions serve only as probes: the model either returns its existing answer or resumes generation from an untouched cache. On MATH, Prune-to-Probe reduces reasoning-token forwards by 2.60%, preserving all naturally correct trajectories while repairing six errors. On MMLU-Pro, it achieves 1.145% pooled savings with no observed harm. Further analysis shows that the intervention captures decision stability rather than correctness (AUROC 0.502). These results demonstrate the potential of causal activation probes for efficient inference-time control without permanent model modification.

arXiv:2611.11032v1cs.LG

Finite-Sample and Communication-Efficient Networked Information Aggregation

Building on SODA 2026 work Kearns et al. (2026), we study learning in directed acyclic graphs in which each agent observes only a subset of the input coordinates and may use the predictions of its parents as additional features. In the finite-sample protocol, the message sent along each edge is the agent's prediction vector on a shared sample, so the communication cost is linear in the sample size $m$. In this paper we study this model under communication constraints. First, we revisit the finite-sample analysis of the full-message protocol. We identify a gap in the finite-sample proof of Kearns et al. (2026) and develop a different argument that establishes a finite-sample population-risk guarantee along paths satisfying deterministic $M$-coverage. Second, we introduce a shared-sketch protocol in which each agent sends a $k$-dimensional linear sketch of its prediction vector instead of the full $m$-dimensional message, where $k\ll m$. We analyze this protocol through a reduction to least squares on the compressed sample together with an oblivious subspace embedding argument. The resulting bound separates statistics from communication: the statistical term is still governed by the original sample size $m$, while the additional error due to compression is controlled by the sketch dimension $k$. For Gaussian sketches, we obtain an explicit high-probability population-risk bound, showing that row subsampling is not the only possible communication-statistics tradeoff for networked information aggregation.

arXiv:2611.11031v1cs.LG

Hybrid Product Search Without the Copy: Lexical, Semantic and Filtered Retrieval Served Directly from a Data Lake

E-commerce catalogs increasingly live in lakehouse tables: Apache Iceberg metadata over Parquet files in object storage. Product search, however, still runs on copies of that catalog, in a lexical engine and a vector database, each with its own ingestion pipeline, schema, staleness window and bill. We show that search applications can be hosted directly on the data lake, with the lakehouse table as the single system of record. We extend Apache Pinot, a real-time OLAP engine that already serves Iceberg tables in place, with BM25 relevance scoring over its Lucene text index, corpus-wide term statistics so that scores are comparable across files, and reciprocal rank fusion in plain SQL; a real-time table fed by a stream can sit behind the same table, merged by the broker. On the Amazon ESCI benchmark (1.2M US products, 22,458 test queries), hybrid search served from the lake matches exact retrieval (nDCG@10 .361). The lake table is queryable 149 s after its files are registered, and a lake commit is searchable in 3.8 s, close to indexing directly into a search engine. On a brand-sorted lake of 277M products (0.8 TB), one 16-vCPU node answers brand-scoped vector, BM25 and client-fused hybrid searches in 6.5-9 ms (p50), sustains 1,100 vector and 635 BM25 searches per second at under 180 ms p99, and makes a commit searchable in 4.3 s. Search adds only its indexes: no copy of the catalog, no sync pipeline and no second schema, which cuts storage, rebuild time and the operational work of keeping copies consistent.

arXiv:2611.11030v1cs.CL

Building and Auditing Chemical Datasets with LLMs: A General LLM-as-a-Judge Framework Applied to Homogeneous Catalytic PET Depolymerisation

Large language models can rapidly extract structured multivariate experimental data from the chemistry literature, yet verifying thousands of generated records without ground truth remains difficult. We present a general, citation-grounded extraction and verification methodology centered on an independent "LLM-as-a-judge", applied to the literature on homogeneous catalytic poly(ethylene terephthalate) (PET) depolymerisation. In this pipeline, an extractor LLM generates schema-enforced records from research papers with citations to document chunks tagged with universally unique identifiers (UUIDs); an independent LLM judge then reads the full paper alongside each record, flags unsupported fields, and proposes cited corrections. Prompt ablations show that requiring chunk-level citations not only provides provenance down to specific paragraphs and tables but also improves extraction accuracy. Before deploying the judge at scale, we benchmarked it against manual evaluation on extractions from a hand-curated reference set of 295 ionic-liquid-catalysed PET glycolysis experiments. The judge agreed with human evaluation on 85.7% of reviewed records and was significantly more effective than a heuristic string-matching baseline at catching errors across related experiments. Deployed across 3,942 extracted records from 561 papers, the framework accepted 67.5% of them as written. Its proposed corrections concentrated on quantitative fields, where the extractor often conflated related experiments. We release the extracted dataset with the complete LLM judge audit logs, as well as the Chemistry Data Extractor Toolkit, an open-source application implementing this end-to-end pipeline in a code-free, browser-based environment for document parsing, customizable schema and prompt design, model-agnostic extraction and auditing, interactive provenance-highlighted review, and reproducible dataset bundling.